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Physics

Revealed: why hot water freezes faster than cold

By Marcus Chown

24 March 2010

Âé¶¹´«Ã½. Science news and long reads from expert journalists, covering developments in science, technology, health and the environment on the website and the magazine.

Freezing depends on impurities (Vilhjalmur Ingi Vilhjalmsson/Getty)

HOT water sometimes freezes faster than cold water – but why? This peculiar phenomenon has baffled scientists for generations, but now there is evidence that the effect may depend on random impurities in the water.

Fast-freezing of hot water is known as the Mpemba effect, after a Tanzanian schoolboy called Erasto Mpemba (see “How the Mpemba effect got its name”). Physicists have come up with several possible explanations, including faster evaporation reducing the volume of hot water, a layer of frost insulating the cooler water, and differing concentration of solutes. But the answer…

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